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• W2113663350 abstract "Prussian Blue analogue (PBA) nanoparticles can be self-assembled at air/liquid interfaces to build novel materials with interesting magnetic features. Herein, we study the influence of the size of PBA Cs0.4 Ni[Cr(CN)6 ]0.9 and K0.25 Ni[Fe(CN)6 ]0.75 nanoparticles on the self-assembly behavior by synchrotron X-ray reflectivity. Both nanoparticles show similar Z-potential values. The phospholipid dipalmitoylphosphatidylcholine and the amino surfactant dimethyldioctadecylammonium have been used as Langmuir monolayers to anchor the PBA nanoparticles and study the interplay of forces directing the self-assembly of the nanoparticles at the surfactant/liquid interface. Whereas Cs0.4 Ni[Cr(CN)6 ]0.9 nanoparticles with a diameter of 8 nm form an incomplete layer at the surfactant/water interface, the larger K0.25 Ni[Fe(CN)6 ]0.75 nanoparticles with a diameter of 20 nm generate complete layers that can be stacked to one another. The size of the PBA nanoparticles is the main parameter determining the final arrangement at the air/liquid interface, due to the different extent of interparticle interaction. This study aims at the rationale design of PBA nanoparticles for an effective interfacial self-assembly, ultimately leading to functional materials." @default.
• W2113663350 created "2016-06-24" @default.
• W2113663350 creator A5000806261 @default.
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• W2113663350 date "2015-07-06" @default.
• W2113663350 modified "2023-09-23" @default.
• W2113663350 title "Self-Assembly Mechanism of Nanoparticles of Ni-Based Prussian Blue Analogues at the Air/Liquid Interface: A Synchrotron X-ray Reflectivity Study" @default.
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• W2113663350 doi "https://doi.org/10.1002/cphc.201500350" @default.
• W2113663350 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26149661" @default.
• W2113663350 hasPublicationYear "2015" @default.
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