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- W2113700207 abstract "A stereospecific synthesis of optically active γ-hydroxy.α,β-unsaturated esters is achieved, involving successively the Sharpless epoxidation of allylic alcohols, oxidation to glycidic acids, conversion into α,β-epoxy diazomethyl ketones, and irradiation in ethanol at 300 nm. Intermediates in the photo-induced rearrangement are epoxy ketenes, which undergo ethanolysis with simultaneous opening of the epoxide, preferably via a transition state involving the s-trans conformation." @default.
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- W2113700207 date "1990-01-01" @default.
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- W2113700207 title "A general stereospecific synthesis of γ-hydroxy-α,β-unsaturated esters" @default.
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- W2113700207 doi "https://doi.org/10.1016/s0040-4039(00)97124-7" @default.
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