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• W2113716213 abstract "The second amorphous-to-crystalline phase transformation in Cu(60)Ti(20)Zr(20) bulk metallic glass was investigated by differential scanning calorimetry and x-ray diffractometry. The difference of the Gibbs free energies between the amorphous phase and the crystalline products during the transformation is estimated to be about 2.46 kJ mol(-1) at 753 K, much smaller than the 61 kJ mol(-1) obtained assuming that it is a polymorphic transformation. It was revealed that the phase transformation occurs through a eutectic crystallization of Cu(51)Zr(14) and Cu(2)TiZr, having an effective activation energy of the order of 400 kJ mol(-1). The average Avrami exponent n is about 2.0, indicating that the crystallization is diffusion controlled." @default.
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• W2113716213 date "2007-05-18" @default.
• W2113716213 modified "2023-09-25" @default.
• W2113716213 title "Second amorphous-to-crystalline phase transformation in Cu₆₀Ti₂₀Zr₂₀bulk metallic glass" @default.
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• W2113716213 doi "https://doi.org/10.1088/0953-8984/19/24/246206" @default.
• W2113716213 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21694050" @default.
• W2113716213 hasPublicationYear "2007" @default.
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