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- W2113721131 abstract "The onset of decomposition of poly(4-methyl-1,3-dioxolane) was lowered to 70°C by 0.1 wt% p-toluene sulfonic acid from 170°C in the absence of acid to produce more than 81% yield of monomer. Protonation forms cyclic oxonium ion followed by depolymerization. Minor products are isomers of hydroxymethyl-2-hydroxyl-2-methyl ethyl ether and bis(2-hydroxyl-2-methyl ethoxyl)methane from rearrangements of the oxonium ions. The first order rate constant of acidolysis of poly(4-methyl-1-1,3-dioxolane) is about 8.5 kcal mol−1, which is much smaller than about 17 kcal mol−1 for the acidolysis of poly(1,3-dioxolane)." @default.
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- W2113721131 date "1987-04-01" @default.
- W2113721131 modified "2023-09-27" @default.
- W2113721131 title "Acidolysis of poly(4-methyl-1,3-dioxolane)" @default.
- W2113721131 doi "https://doi.org/10.1002/pola.1987.080250401" @default.
- W2113721131 hasPublicationYear "1987" @default.
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