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• W2113815079 abstract "Lithium nitrate has been used to prevent and to mediate the expansion caused by alkali‐silica reaction (ASR). However, there is limited information on how it affects the existing reaction products caused by ASR. The aim of the present work is to determine the modifications caused by the LiNO 3 treatment on the structure of the gel produced by ASR. ASR gel samples obtained from a concrete dam were exposed to an aqueous solution of lithium nitrate and sodium hydroxide with molar LiNO 3 / NaOH=0.74, and the resulting products were analyzed by X‐ray diffraction, infrared spectroscopy, and solid‐state nuclear magnetic resonance of 29 Si, 23 Na, and 7 Li. The treatment of the gel samples produces significant structural modifications in ASR products. A new amorphous silicate compound incorporating Li + ions is formed, with an average silicate network that can be described as linear in contrast with the layered structure of the original gel. This elimination of the layered structure after the Li‐based treatments may be related to the reduction of the tendency of the gel to expand. Also, several crystalline compounds containing potassium indicate the release of this species from the original ASR gel." @default.
• W2113815079 created "2016-06-24" @default.
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• W2113815079 date "2008-10-01" @default.
• W2113815079 modified "2023-10-18" @default.
• W2113815079 title "Effect of Lithium Nitrate on the Alkali-Silica Reaction Gel" @default.
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• W2113815079 doi "https://doi.org/10.1111/j.1551-2916.2008.02638.x" @default.
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