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- W2113819515 abstract "Three barrel-shaped artificial molecular capsules 1-3, based on normal cucurbit[5]uril (Q[5]) and decamethylcucurbit[5]uril (Me10Q[5]), were synthesized and structurally characterized by single-crystal X-ray diffraction. Encapsulation of a chlorine anion in the cavity of a Q[5] or Me10Q[5] to form closed a molecular capsule with the coordinated metal ions or coordinated metal ions and water molecules in the crystal structures of these compounds is common. The three complexes [Pr2(C30H30N20O10)Cl3(H2O)13]3+3Cl-·5H2O (1), [Sr2(C40H50N20O10)(H2O)4Cl]3+3Cl-·2(HCl) 19H2O (2) and [K(C40H50N20O10)(H2O)Cl]·[Zn(H2O)2Cl2]·[ZnCl4]2-·2(H3O)+·8H2O (3) all crystallize as isolated molecular capsules." @default.
- W2113819515 created "2016-06-24" @default.
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- W2113819515 date "2007-06-06" @default.
- W2113819515 modified "2023-09-30" @default.
- W2113819515 title "Chlorine Anion Encapsulation by Molecular Capsules Based on Cucurbit[5]uril and Decamethylcucurbit[5]uril" @default.
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- W2113819515 doi "https://doi.org/10.3390/12071325" @default.
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