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• W2113820986 abstract "Jekyll and Hyde: Pinches of LiCl can catalyze orthometalations of halogen-substituted arenes and addition reactions of unsaturated esters, mediated by lithium diisopropylamide. Larger salt portions can transform weak organometallic bases (e.g., Grignard reagents, zincates) into “turbo” reagents of high reactivity and functional group tolerance. But the presence of LiCl, especially as an overlooked metathesis by-product can be detrimental to other catalytic reactions." @default.
• W2113820986 created "2016-06-24" @default.
• W2113820986 creator A5022562955 @default.
• W2113820986 creator A5034242651 @default.
• W2113820986 date "2011-06-22" @default.
• W2113820986 modified "2023-10-12" @default.
• W2113820986 title "Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes" @default.
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• W2113820986 doi "https://doi.org/10.1002/anie.201102054" @default.
• W2113820986 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21698730" @default.
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