Matches in SemOpenAlex for { <https://semopenalex.org/work/W2113882249> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2113882249 endingPage "272" @default.
- W2113882249 startingPage "256" @default.
- W2113882249 abstract "Conformational preferences of two classes of organometal complexes have been surveyed by inspecting the Cambridge Structural Database (CSD). Lewis acid carbonyl complexes demonstrate a variety of coordination geometries, depending on the electronic and steric requirements of the carbonyl ligands and the nature of the Lewis acid. Similarly, the solid-state conformation of various π-bonding ligands in metal acyl, metal nitrosyl, metal acetylene, and metal imido complexes is revealed. These insights have stimulated the development of a conformational model that is based on considerations of π-bond hybridization and frontier molecular orbital theory. The analyses are relevant to the mechanism and transition structures of many synthetically important transformations. A deeper understanding of the conformational properties of organometal complexes, based on accurate structural information, will likely expedite the design and improvement of metal-mediated processes." @default.
- W2113882249 created "2016-06-24" @default.
- W2113882249 creator A5015325922 @default.
- W2113882249 creator A5033042067 @default.
- W2113882249 creator A5035618234 @default.
- W2113882249 date "1990-03-01" @default.
- W2113882249 modified "2023-10-17" @default.
- W2113882249 title "On the Conformation and Structure of Organometal Complexes in the Solid State: Two Studies Relevant to Chemical Synthesis" @default.
- W2113882249 doi "https://doi.org/10.1002/anie.199002561" @default.
- W2113882249 hasPublicationYear "1990" @default.
- W2113882249 type Work @default.
- W2113882249 sameAs 2113882249 @default.
- W2113882249 citedByCount "174" @default.
- W2113882249 countsByYear W21138822492012 @default.
- W2113882249 countsByYear W21138822492013 @default.
- W2113882249 countsByYear W21138822492014 @default.
- W2113882249 countsByYear W21138822492015 @default.
- W2113882249 countsByYear W21138822492016 @default.
- W2113882249 countsByYear W21138822492017 @default.
- W2113882249 countsByYear W21138822492018 @default.
- W2113882249 countsByYear W21138822492019 @default.
- W2113882249 countsByYear W21138822492020 @default.
- W2113882249 countsByYear W21138822492021 @default.
- W2113882249 countsByYear W21138822492022 @default.
- W2113882249 countsByYear W21138822492023 @default.
- W2113882249 crossrefType "journal-article" @default.
- W2113882249 hasAuthorship W2113882249A5015325922 @default.
- W2113882249 hasAuthorship W2113882249A5033042067 @default.
- W2113882249 hasAuthorship W2113882249A5035618234 @default.
- W2113882249 hasConcept C106773901 @default.
- W2113882249 hasConcept C107814960 @default.
- W2113882249 hasConcept C139358910 @default.
- W2113882249 hasConcept C147597530 @default.
- W2113882249 hasConcept C147789679 @default.
- W2113882249 hasConcept C161790260 @default.
- W2113882249 hasConcept C163638829 @default.
- W2113882249 hasConcept C178790620 @default.
- W2113882249 hasConcept C185592680 @default.
- W2113882249 hasConcept C201194858 @default.
- W2113882249 hasConcept C21951064 @default.
- W2113882249 hasConcept C2777517455 @default.
- W2113882249 hasConcept C32909587 @default.
- W2113882249 hasConcept C544153396 @default.
- W2113882249 hasConcept C68913812 @default.
- W2113882249 hasConcept C71240020 @default.
- W2113882249 hasConceptScore W2113882249C106773901 @default.
- W2113882249 hasConceptScore W2113882249C107814960 @default.
- W2113882249 hasConceptScore W2113882249C139358910 @default.
- W2113882249 hasConceptScore W2113882249C147597530 @default.
- W2113882249 hasConceptScore W2113882249C147789679 @default.
- W2113882249 hasConceptScore W2113882249C161790260 @default.
- W2113882249 hasConceptScore W2113882249C163638829 @default.
- W2113882249 hasConceptScore W2113882249C178790620 @default.
- W2113882249 hasConceptScore W2113882249C185592680 @default.
- W2113882249 hasConceptScore W2113882249C201194858 @default.
- W2113882249 hasConceptScore W2113882249C21951064 @default.
- W2113882249 hasConceptScore W2113882249C2777517455 @default.
- W2113882249 hasConceptScore W2113882249C32909587 @default.
- W2113882249 hasConceptScore W2113882249C544153396 @default.
- W2113882249 hasConceptScore W2113882249C68913812 @default.
- W2113882249 hasConceptScore W2113882249C71240020 @default.
- W2113882249 hasIssue "3" @default.
- W2113882249 hasLocation W21138822491 @default.
- W2113882249 hasOpenAccess W2113882249 @default.
- W2113882249 hasPrimaryLocation W21138822491 @default.
- W2113882249 hasRelatedWork W1558163028 @default.
- W2113882249 hasRelatedWork W1965238818 @default.
- W2113882249 hasRelatedWork W1968899056 @default.
- W2113882249 hasRelatedWork W2071122984 @default.
- W2113882249 hasRelatedWork W2090391251 @default.
- W2113882249 hasRelatedWork W3210191542 @default.
- W2113882249 hasRelatedWork W4233837758 @default.
- W2113882249 hasRelatedWork W4294723901 @default.
- W2113882249 hasRelatedWork W4310690213 @default.
- W2113882249 hasRelatedWork W4319317547 @default.
- W2113882249 hasVolume "29" @default.
- W2113882249 isParatext "false" @default.
- W2113882249 isRetracted "false" @default.
- W2113882249 magId "2113882249" @default.
- W2113882249 workType "article" @default.