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• W2113882277 abstract "[110769-32-9] C17H22CuLi2NSi2 (MW 373.97)InChI = 1S/2C8H11Si.CN.Cu.2Li/c2*1-9(2)8-6-4-3-5-7-8;1-2;;;/h2*3-7H,1-2H3;;;;/q;;;-2;2*+1InChIKey = ADZKFQKKOLYIFV-UHFFFAOYSA-N(higher-order copper reagent for transfer of a dimethylphenylsilyl group to enones, allenes, alkynes, epoxides, and alkyl halides)Physical Data: relatively stable reagent at rt; usually prepared in situ at 0 °C.Solubility: sol THF (−78 °C and above).Preparative Methods: prepared1 by adding 0.5 equiv of dry Copper(I) Cyanide to dimethylphenylsilyllithium in THF (eq 1), which in turn is generated from Chlorodimethylphenylsilane and Lithium metal. Analogous bis(trimethylsilyl)cyanocuprates are prepared in a similar manner. (1)More detail for the preparation of this and related reagents may be found in Fleming, I. In Organocopper Reagents: A Practical Approach; Taylor, R. J. K., Ed.; OUP: Oxford, 1994; Chapter 12, pp 257–292.Handling, Storage, and Precautions: cannot be stored or isolated. Care must be taken to avoid oxygen and moisture in the reaction system. Use in a fume hood." @default.
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• W2113882277 date "2008-09-15" @default.
• W2113882277 modified "2023-09-24" @default.
• W2113882277 title "Dilithium Cyanobis(dimethylphenylsilyl)cuprate" @default.
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• W2113882277 doi "https://doi.org/10.1002/047084289x.rd265m.pub2" @default.
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