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- W2113922849 abstract "Although use of carbohydrates to install the required stereocenters is a rela-tively effective strategy, better, more efficient, and unified syn-thetic pathways to these ophiocerins could be devised if starting materials other than carbohydrates, with set stereochemical cen-ters, were utilized. Since carbohydrate-based approaches must include the destruction or conversion of unnecessary or incorrect stereocenters, more direct synthetic routes were sought out in which ophiocerins could be secured by creating the required stereochemistry after synthesizing the tetrahydropyran ring.The general synthetic strategy presented herein is shown in the following retrosynthetic analysis (Scheme 1). The ophio-cerins could be derived from dihydropyran derivative" @default.
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- W2113922849 date "2010-03-20" @default.
- W2113922849 modified "2023-10-16" @default.
- W2113922849 title "Synthesis of Ophiocerins from Non-Carbohydrate Sources" @default.
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- W2113922849 doi "https://doi.org/10.5012/bkcs.2010.31.03.555" @default.
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