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- W2113990538 abstract "Abstract The standard enthalpies of formation of some crystalline copper(II) complexes were obtained from solution-reaction calorimetric measurements and the enthalpies of sublimation of Cu2(acetate)4, Cu(dmg)2 and Cu(PhNacac)2 were obtained from torsion-Knudsen vapour pressure measurements. The differences between the mean Cu-ligand and H-ligand dissociation enthalpies were derived and are given below. a . Complex a ΔfHmXXX(cr)(kJmol−1) ΔHmXXX(sub)(kJmol−1) tD(Cu-L)-D(H-L)(kJmol−1) Cu2(acetate)4 −1765.8 ± 2.7 106.1 ± 0.9 −67.1 ± 1.8 Cu(dmg)2 −171.5 ± 2.3 93.1 ± 0.8 −63.7 ± 1.8 Cu(PhNacac)2 −174.3 ± 2.7 128.1 ± 0.8 −92.3 ± 3.7 Cu(gly)2 −940.8 ± 1.7 111 ± 15 −26.3 ± 7.7 a Hdmg, Dimethylglyoxime; Hgly, glycine; PhNacacH, 4-phenylamino-3-penten-2-one." @default.
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- W2113990538 date "1990-04-01" @default.
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- W2113990538 title "Mean copper-ligand binding enthalpies in copper(II) complexes of dimethylglyoxime, glycine, acetic acid and 4-phenylamino-3-penten-2-one" @default.
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- W2113990538 doi "https://doi.org/10.1016/0040-6031(90)80266-2" @default.
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