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- W2113994088 abstract "Trifluoroacetic anhydride-mediated tandem trifluoroacetylation/cyclization of cyanoacetanilides proceeded efficiently under mild conditions to give 4-hydroxy-3-trifluoroacetylquinolin-2(1H)-ones in good yields. Isolation and direct observation of the reaction intermediates revealed that α-trifluoroacetylation resulted in the shortening of C≡N bonds and that the electron density of CN groups was high. A plausible reaction mechanism based on the results is also described." @default.
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- W2113994088 date "2010-03-23" @default.
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- W2113994088 title "Trifluoroacetylation-Induced Houben−Hoesch-Type Cyclization of Cyanoacetanilides: Increased Nucleophilicity of CN Groups" @default.
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- W2113994088 doi "https://doi.org/10.1021/jo100220m" @default.
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