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• W2114008894 abstract "Electron spin echo experiment on photo-induced radical pairs in photosynthetic reaction centers produces the echo signal which is out-of-phase due to spin coherence. This signal is strongly modulated because of the electron spin-spin dipolar and exchange couplings in the pair. Fourier transformation of the time-domain modulation produces a “Pake doublet” from the two coupled spins, which allows the accurate determination of the distance between the two radicals. The precision with which the distance can be measured is 0.3 – 0.4 Å, for radicals separated in the pair by ~ 30 Å. This high precision provides a very sensitive tool for structural investigations in photosynthetic reaction centers. The method is applicable to spin-correlated radical pairs separated by 20 – 40 Å and possessing an EPR linewidth accessible for the full excitation by the microwave pulses." @default.
• W2114008894 created "2016-06-24" @default.
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• W2114008894 date "2002-01-01" @default.
• W2114008894 modified "2023-09-23" @default.
• W2114008894 title "Photo-Induced Radical Pairs Investigated Using Out-Of-Phase Electron Spin Echo" @default.
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• W2114008894 doi "https://doi.org/10.1007/0-306-47109-4_13" @default.
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