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- W2114037247 abstract "Abstract The results of ac electrical conductivity and DSC calorimetry measurements on the Li2SO4Li2WO4 system show two solid-phase transitions at 572 and 595°C. The maximum conductivity and the minimum total molar enthalpy of transition occur at 90 mole% Li2SO4. The total molar enthalpy of transition shows a maximum at 67–68 mole% Li2SO4. There is no evidence of melting up to 650°C over the complete composition range. Assuming WO2−4 to be incorporated as guest ion in the SO2−4 sublattice in Li2SO4-rich compositions the enhanced conductivity effect for the Li 2 SO 4 WO 4 composition is interpreted as convincing evidence that the anion-rotation-assisted movement of cations or “paddle-wheel” mechanism does not contribute significantly to fast Li+ ion conductivity in Li2SO4-based compositions. These results are consistent with the interpretation of fast ion transport in Na2SO4-based compositions via a percolation-type mechanism where lattice “free volume” plays a predominant role." @default.
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- W2114037247 date "1989-07-01" @default.
- W2114037247 modified "2023-10-03" @default.
- W2114037247 title "Ionic conductivity and solid-phase transitions in Li2SO4Li2WO4 system relating to ion transport mechanism" @default.
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- W2114037247 doi "https://doi.org/10.1016/0022-4596(89)90202-8" @default.
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