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- W2114327317 abstract "X-Ray and ultraviolet photoelectron spectroscopies (XPS and UPS), Auger electron spectroscopy (AES) and thermal desorption spectroscopy (TDS) have been used to study the coadsorption of CO and U on polycrystalline Pd. We investigated the modification of the electronic structure of Pd at low U coverages and the mode of CO chemisorption (dissociative vs. associative) as a function of surface U concentration. U adsorption results in the narrowing of the Pd 4d band. At low U coverages the density of states (DOS) at the Fermi level decreases and the U 5f electrons are localized. The CO saturation coverage at room temperature decreases with increasing U surface concentration, while CO adsorption at –165 °C is less affected. This is attributed mainly to a decrease of CO chemisorption energy but also to blocking of Pd adsorption sites by U. A. decrease in the heat of chemisorption for CO is explained by a change of the electronic structure of Pd by U. At low dosage U itself loses most of its reactivity, probably because of U—Pd solid-state bonding and below a critical U surface concentration CO dissociation becomes an activated process. High-temperature reaction between CO and U-covered surfaces leads to the partial transformation of U into a surface oxycarbide. In the presence of this compound some CO is chemisorbed strongly on the surface and is stable even at 300 °C, in contrast to CO on Pd metal. A similar effect has also been observed for classical promoters such as the alkali metals." @default.
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- W2114327317 date "1994-01-01" @default.
- W2114327317 modified "2023-09-25" @default.
- W2114327317 title "Modification of the electronic structure of Pd by U films: chemisorption of CO" @default.
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- W2114327317 doi "https://doi.org/10.1039/ft9949001285" @default.
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