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• W2114431072 abstract "A new Anderson polyoxometalate (H3O)[(3-C5H7N2)2(Cr(OH)6Mo6O18)] · 3H2O (3-C5H6N2 = 3-aminopyridine) was hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Crystal data: triclinic, P 1, a = 7.8482(8) Å, b = 10.1800(10) Å, c = 10.4103(10) Å, α = 88.031(3)°, β = 78.308(2)°, γ = 88.842(3)°, V = 813.91 Å3, Z = 1, R(F) = 0.0397, wR ref(F 2) = 0.1022, and S = 1.076. The X-ray crystallographic study showed that the structure contains Anderson-type [Cr(OH)6Mo6O18]3− polyoxoanions. The title compound has high catalytic activity for the oxidation of acetone tested in a continuous-flow fixed-bed micro-reactor. When the initial concentration is 18.3 g m−3 in air and the flow velocity is 8.5 mL min−1, the acetone is completely eliminated at 160°C." @default.
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• W2114431072 date "2011-08-12" @default.
• W2114431072 modified "2023-09-22" @default.
• W2114431072 title "A novel Anderson-type polyoxometalate: hydrothermal synthesis, crystal structure, and catalytic performance of (H₃O)[(3-C₅H₇N₂)₂(Cr(OH)₆Mo₆O₁₈)] · 3H₂O" @default.
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• W2114431072 doi "https://doi.org/10.1080/00958972.2011.607897" @default.
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