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- W2114484958 endingPage "14260" @default.
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- W2114484958 abstract "Fluorination: A wide range of nitroolefins and pyrazol-5-ones undergo a sequential 1,4-addition/dearomative-fluorination transformation when treated with a catalytic amount of a tertiary-amine—thiourea compound and the terminal electrophile, N-fluorobenzenesulfonimide, to give fluorinated products in 72–95 % yield with up to 99:1 d.r. and 98 % ee. Notably, these products contain adjacent tertiary and α-fluoro quaternary stereocenters (see scheme)." @default.
- W2114484958 created "2016-06-24" @default.
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- W2114484958 date "2012-10-09" @default.
- W2114484958 modified "2023-10-18" @default.
- W2114484958 title "Highly Diastereo- and Enantioselective Organocatalytic One-Pot Sequential 1,4-Addition/Dearomative-Fluorination Transformation" @default.
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- W2114484958 doi "https://doi.org/10.1002/chem.201202636" @default.
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