Matches in SemOpenAlex for { <https://semopenalex.org/work/W2114499990> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2114499990 endingPage "120" @default.
- W2114499990 startingPage "115" @default.
- W2114499990 abstract "(PPh4)[(ReO2S2)CuI] (1) und (NEt4)2[(ReOS3)Cu3Cl4] (2), die die bisher nicht isolierten Oxothioperrhenat-Ionen [ReO2S2]− und [ReOS3]− als Liganden enthalten, wurden durch Reaktion von (NEt4)[ReS4] mit PPh3 und CuI in Aceton in Gegenwart von (PPh4)I ((1) bzw. entsprechend mit CuCl in CH2Cl2 in Gegenwart von (NEt4)Cl ((2) erhalten. 1 und 2 wurden durch Einkristall-Röntgenstrukturanalyse, Elementaranalyse, sowie spektroskopische Untersuchungen (IR, UV/Vis) charakterisiert. In den Elektronenspektren findet man Banden, die interessanten niederenergetischen Charge-Transfer-Übergängen des Typs d(Cu) → d(Re) näherungsweise zugeordnet werden können. Kristalldaten: P21/n, a = 1162,2(4), b = 1395,7(6), c = 1612,3(9)pm, β = 96,53(4)° V = 2598(2) · 106pm3, R = 0,049 für 4623 unabhängige Reflexe (F0≥4,0σ(F0)). C2/c, a = 2059,0(5), b = 1352,9(3), c = 2217,1(5)pm, β = 90,26(22)° V = 6176(2) · 106pm3, R = 0,080 für 3162 unabhängige Reflexe (F0≥4,0σ(F0)). (PPh4)[(ReO2S2)CuI] and (NEt4)2[ReOS3)Cu3Cl4]: Fixation of the up to now not Isolated Ions [ReO2S2]− and [ReOS3]− Utilizing the Stability of the CuS2(Re) and Cu3S3(Re) Fragments (PPh4)[(ReO2S2)CuI] (1) and (NEt4)2[ReOS3)Cu3Cl4] (2) containing the up to now not isolated oxothioperrhenate ions [ReO2S2]− and [ReOS3]− as ligands, have been prepared by the reaction of (NEt4)[ReS4] with PPh3 and CuI in acetone in the presence of (PPh4)I ((1)) or with CuCl in CH2Cl2 in the presence of (NEt4)Cl ((2)), respectively. 1 and 2 have been characterized by X-ray structure analysis, elemental analysis and spectroscopic studies (IR, UV/Vis). The electronic spectra show bands which can approximately be assigned to interesting low-energy charge-transfer-transitions of the type d(Cu) → d(Re). For crystal data see Inhaltsübersicht." @default.
- W2114499990 created "2016-06-24" @default.
- W2114499990 creator A5004991736 @default.
- W2114499990 creator A5014503882 @default.
- W2114499990 creator A5040200036 @default.
- W2114499990 creator A5045582390 @default.
- W2114499990 creator A5071057174 @default.
- W2114499990 creator A5090417342 @default.
- W2114499990 date "1992-08-01" @default.
- W2114499990 modified "2023-09-27" @default.
- W2114499990 title "(PPh4)[(ReO2S2)CuI] und (NEt4)2[(ReOS3)Cu3Cl4]: Fixierung der bisher nicht isolierten Ionen [ReO2S2]? und [ReOS3]? durch Ausnutzung der Stabilit�t der CuS2(Re)- und Cu3S3(Re)-Fragmente" @default.
- W2114499990 cites W1554090903 @default.
- W2114499990 cites W1970912843 @default.
- W2114499990 cites W1971793340 @default.
- W2114499990 cites W1974189440 @default.
- W2114499990 cites W1983645920 @default.
- W2114499990 cites W1988155151 @default.
- W2114499990 cites W1999972567 @default.
- W2114499990 cites W2000406134 @default.
- W2114499990 cites W2008174298 @default.
- W2114499990 cites W2011417457 @default.
- W2114499990 cites W2014067830 @default.
- W2114499990 cites W2018489787 @default.
- W2114499990 cites W2023562295 @default.
- W2114499990 cites W2029690127 @default.
- W2114499990 cites W2029956570 @default.
- W2114499990 cites W2030906220 @default.
- W2114499990 cites W2033180633 @default.
- W2114499990 cites W2042905502 @default.
- W2114499990 cites W2054455316 @default.
- W2114499990 cites W2057168862 @default.
- W2114499990 cites W2059217453 @default.
- W2114499990 cites W2061724372 @default.
- W2114499990 cites W2063194174 @default.
- W2114499990 cites W2065024179 @default.
- W2114499990 cites W2065062586 @default.
- W2114499990 cites W2074087948 @default.
- W2114499990 cites W2077027202 @default.
- W2114499990 cites W2079320288 @default.
- W2114499990 cites W2084372137 @default.
- W2114499990 cites W2085544123 @default.
- W2114499990 cites W2088591799 @default.
- W2114499990 cites W2089779704 @default.
- W2114499990 cites W2091348814 @default.
- W2114499990 cites W2094995212 @default.
- W2114499990 cites W2108849945 @default.
- W2114499990 cites W2117206348 @default.
- W2114499990 cites W2145818582 @default.
- W2114499990 cites W2245244670 @default.
- W2114499990 cites W276019359 @default.
- W2114499990 cites W3138961949 @default.
- W2114499990 doi "https://doi.org/10.1002/zaac.19926140820" @default.
- W2114499990 hasPublicationYear "1992" @default.
- W2114499990 type Work @default.
- W2114499990 sameAs 2114499990 @default.
- W2114499990 citedByCount "5" @default.
- W2114499990 countsByYear W21144999902014 @default.
- W2114499990 crossrefType "journal-article" @default.
- W2114499990 hasAuthorship W2114499990A5004991736 @default.
- W2114499990 hasAuthorship W2114499990A5014503882 @default.
- W2114499990 hasAuthorship W2114499990A5040200036 @default.
- W2114499990 hasAuthorship W2114499990A5045582390 @default.
- W2114499990 hasAuthorship W2114499990A5071057174 @default.
- W2114499990 hasAuthorship W2114499990A5090417342 @default.
- W2114499990 hasConcept C155647269 @default.
- W2114499990 hasConcept C185592680 @default.
- W2114499990 hasConcept C71240020 @default.
- W2114499990 hasConceptScore W2114499990C155647269 @default.
- W2114499990 hasConceptScore W2114499990C185592680 @default.
- W2114499990 hasConceptScore W2114499990C71240020 @default.
- W2114499990 hasIssue "8" @default.
- W2114499990 hasLocation W21144999901 @default.
- W2114499990 hasOpenAccess W2114499990 @default.
- W2114499990 hasPrimaryLocation W21144999901 @default.
- W2114499990 hasRelatedWork W2329438784 @default.
- W2114499990 hasRelatedWork W2331024552 @default.
- W2114499990 hasRelatedWork W2605421943 @default.
- W2114499990 hasRelatedWork W2606304347 @default.
- W2114499990 hasRelatedWork W2606340465 @default.
- W2114499990 hasRelatedWork W2606739995 @default.
- W2114499990 hasRelatedWork W2606776574 @default.
- W2114499990 hasRelatedWork W2606792798 @default.
- W2114499990 hasRelatedWork W2607123153 @default.
- W2114499990 hasRelatedWork W2950861082 @default.
- W2114499990 hasVolume "614" @default.
- W2114499990 isParatext "false" @default.
- W2114499990 isRetracted "false" @default.
- W2114499990 magId "2114499990" @default.
- W2114499990 workType "article" @default.