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- W2114533504 abstract "The compounds Sr3MRhO6(M=Y, Sc, In) have been synthesized and structurally characterized by Rietveld refinement of powder X-ray diffraction data in the space groupR3c;Z=6. The lattice parameters for the series were found to bea=9.7598(1) Å andc=11.3152(1) Å,a=9.6833(1) Å andc=11.0478(2) Å, anda=9.6473(1) Å andc=11.3597(1) Å, for Sr3YRhO6, Sr3ScRhO6, and Sr3InRhO6, respectively. Thermogravimetric analysis indicates that these phases are stoichiometric rhodium(III) oxides. The oxygen content was determined to be 6.00(2), 6.05(2), and 5.99(2), for Sr3MRhO6(M=Y, Sc, In), respectively. These compounds are isostructural with K4CdCl6. The structure consists of infinite one-dimensional chains of alternating face-shared RhO6octahedra andMO6trigonal prisms (M=Y, Sc, In). The strontium cations are located in a distorted square antiprismatic environment." @default.
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- W2114533504 date "1998-09-01" @default.
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- W2114533504 title "Synthesis and Characterization of New Rh(III) Compounds with the K4CdCl6Structure-Type: Sr3MRhO6(M=Y, Sc, In)" @default.
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- W2114533504 doi "https://doi.org/10.1006/jssc.1998.7877" @default.
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