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- W2114555208 abstract "A novel class of metal organic frameworks (MOFs) has been synthesized from Cu-acetate and dicarboxylic acids using liquid phase epitaxy. The SURMOF-2 isoreticular series exhibits P4 symmetry, for the longest linker a channel-size of 3 × 3 nm2 is obtained, one of the largest values reported for any MOF so far. High quality, ab-initio electronic structure calculations confirm the stability of a regular packing of (Cu++)2- carboxylate paddle-wheel planes with P4 symmetry and reveal, that the SURMOF-2 structures are in fact metastable, with a fairly large activation barrier for the transition to the bulk MOF-2 structures exhibiting a lower, twofold (P2 or C2) symmetry. The theoretical calculations also allow identifying the mechanism for the low-temperature epitaxial growth process and to explain, why a synthesis of this highly interesting, new class of high-symmetry, metastable MOFs is not possible using the conventional solvothermal process." @default.
- W2114555208 created "2016-06-24" @default.
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- W2114555208 date "2012-12-04" @default.
- W2114555208 modified "2023-09-30" @default.
- W2114555208 title "A novel series of isoreticular metal organic frameworks: realizing metastable structures by liquid phase epitaxy" @default.
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- W2114555208 doi "https://doi.org/10.1038/srep00921" @default.
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