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- W2114584789 abstract "The asymmetric reduction of ketones by oxido-reductases is often limited by poor solubility of the substrates. We have explored the use of heptakis-(2,6-di-O-methyl)-β-cyclodextrin (DIMEB) to resolve this problem. The solubility of the poorly water soluble 2-acetylnaphthalene and the corresponding 1-(2-naphthyl)ethanol in DIMEB buffer was up to 147 fold higher than in buffer alone. The dissociation constants (KDiss) of the DIMEB complexes and the kinetics of the asymmetric reduction were determined. Batch reductions reached high yields with excellent enantioselectivity and were simulated with good agreement using the values of KDISS and the kinetic parameters. The oxido-reductases used for preparative reductions, Candida parapsilosis carbonyl reductase (CPCR) and formate dehydrogenase (FDH), showed no DIMEB-induced deactivation." @default.
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- W2114584789 date "1997-01-01" @default.
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- W2114584789 title "Asymmetric Enzymatic Reduction of Lipophilic Ketones in Aqueous Solution Containing Cyclodextrins" @default.
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- W2114584789 doi "https://doi.org/10.3109/10242429709003610" @default.
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