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- W2114787239 abstract "An alkyne-containing multiple aromatic ether-linked phthalonitrile has been synthesized and characterized. The oligomeric phthalonitrile monomer was prepared from the reaction of an excess amount of bisphenol A with 4,4′-dibromotolane in the presence of K2CO3 in a N,N-dimethylformamide/toluene solvent mixture, followed by end-capping with 4-nitrophthalonitrile in a two-step, one-pot reaction. After being cured in the presence of bis(4-[4-aminophenoxy]phenyl)sulfone, the polymeric properties of the alkyne- and non-alkyne-containing oligomeric phthalonitrile resins were compared. Rheometric measurements and thermogravimetric analysis showed that the alkyne-containing oligomeric phthalonitrile resin had better mechanical properties than an analogous non-alkyne-containing resin cured under identical conditions and exhibited excellent thermal and oxidative properties. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4774–4778" @default.
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- W2114787239 date "2013-08-26" @default.
- W2114787239 modified "2023-10-18" @default.
- W2114787239 title "Alkyne-containing phthalonitrile resins: Controlling mechanical properties by selective curing" @default.
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- W2114787239 doi "https://doi.org/10.1002/pola.26899" @default.
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