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- W2114802273 endingPage "4003" @default.
- W2114802273 startingPage "3994" @default.
- W2114802273 abstract "Acceptorless dehydrogenation of alcohols, an important organic transformation, was accomplished with well-defined and inexpensive iron-based catalysts supported by a cooperating PNP pincer ligand. Benzylic and aliphatic secondary alcohols were dehydrogenated to the corresponding ketones in good isolated yields upon release of dihydrogen. Primary alcohols were dehydrogenated to esters and lactones, respectively. Mixed primary/secondary diols were oxidized at the secondary alcohol moiety with good chemoselectivity. The mechanism of the reaction was investigated using both experiment and DFT calculations, and the crucial role of metal–ligand cooperativity in the reaction was elucidated. The iron complexes are also excellent catalysts for the hydrogenation of challenging ketone substrates at ambient temperature under mild H2 pressure, the reverse of secondary alcohol dehydrogenation." @default.
- W2114802273 created "2016-06-24" @default.
- W2114802273 creator A5044532043 @default.
- W2114802273 creator A5045762965 @default.
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- W2114802273 creator A5068099743 @default.
- W2114802273 creator A5075267933 @default.
- W2114802273 creator A5081856061 @default.
- W2114802273 creator A5082941087 @default.
- W2114802273 date "2014-10-10" @default.
- W2114802273 modified "2023-10-18" @default.
- W2114802273 title "Well-Defined Iron Catalysts for the Acceptorless Reversible Dehydrogenation-Hydrogenation of Alcohols and Ketones" @default.
- W2114802273 cites W1965435179 @default.
- W2114802273 cites W1968156775 @default.
- W2114802273 cites W1969705463 @default.
- W2114802273 cites W1970800627 @default.
- W2114802273 cites W1972768193 @default.
- W2114802273 cites W1972957600 @default.
- W2114802273 cites W1976208697 @default.
- W2114802273 cites W1984280482 @default.
- W2114802273 cites W1985047807 @default.
- W2114802273 cites W1988056791 @default.
- W2114802273 cites W1990064600 @default.
- W2114802273 cites W1993954445 @default.
- W2114802273 cites W2000466466 @default.
- W2114802273 cites W2003946789 @default.
- W2114802273 cites W2004200493 @default.
- W2114802273 cites W2009626516 @default.
- W2114802273 cites W2013613760 @default.
- W2114802273 cites W2018014134 @default.
- W2114802273 cites W2018036572 @default.
- W2114802273 cites W2027355711 @default.
- W2114802273 cites W2027365329 @default.
- W2114802273 cites W2032294243 @default.
- W2114802273 cites W2033383024 @default.
- W2114802273 cites W2038808854 @default.
- W2114802273 cites W2039946456 @default.
- W2114802273 cites W2041067432 @default.
- W2114802273 cites W2041794762 @default.
- W2114802273 cites W2042786605 @default.
- W2114802273 cites W2050592102 @default.
- W2114802273 cites W2050979151 @default.
- W2114802273 cites W2052070104 @default.
- W2114802273 cites W2053863270 @default.
- W2114802273 cites W2054495408 @default.
- W2114802273 cites W2054994580 @default.
- W2114802273 cites W2062493436 @default.
- W2114802273 cites W2064070180 @default.
- W2114802273 cites W2073669612 @default.
- W2114802273 cites W2076320031 @default.
- W2114802273 cites W2082696408 @default.
- W2114802273 cites W2084616510 @default.
- W2114802273 cites W2085736412 @default.
- W2114802273 cites W2088144901 @default.
- W2114802273 cites W2089796475 @default.
- W2114802273 cites W2091278837 @default.
- W2114802273 cites W2095417590 @default.
- W2114802273 cites W2104878427 @default.
- W2114802273 cites W2105195542 @default.
- W2114802273 cites W2108315037 @default.
- W2114802273 cites W2108743735 @default.
- W2114802273 cites W2110795108 @default.
- W2114802273 cites W2112989618 @default.
- W2114802273 cites W2113233629 @default.
- W2114802273 cites W2114419242 @default.
- W2114802273 cites W2115496359 @default.
- W2114802273 cites W2121091156 @default.
- W2114802273 cites W2122891931 @default.
- W2114802273 cites W2124810596 @default.
- W2114802273 cites W2129290101 @default.
- W2114802273 cites W2133517549 @default.
- W2114802273 cites W2136950527 @default.
- W2114802273 cites W2146165919 @default.
- W2114802273 cites W2147247840 @default.
- W2114802273 cites W2147633475 @default.
- W2114802273 cites W2150971186 @default.
- W2114802273 cites W2156622309 @default.
- W2114802273 cites W2157241739 @default.
- W2114802273 cites W2161404682 @default.
- W2114802273 cites W2164396975 @default.
- W2114802273 cites W2168471316 @default.
- W2114802273 cites W2169146772 @default.
- W2114802273 cites W2169170653 @default.
- W2114802273 cites W2170100713 @default.
- W2114802273 cites W2178345059 @default.
- W2114802273 cites W2180075791 @default.
- W2114802273 cites W2313038642 @default.
- W2114802273 cites W2313327466 @default.
- W2114802273 cites W2313438091 @default.
- W2114802273 cites W2314704228 @default.
- W2114802273 cites W2315542586 @default.
- W2114802273 cites W2315899748 @default.
- W2114802273 cites W2316261853 @default.
- W2114802273 cites W2316679889 @default.
- W2114802273 cites W2317433266 @default.
- W2114802273 cites W2318959109 @default.
- W2114802273 cites W2320916201 @default.