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- W2114865999 startingPage "17355" @default.
- W2114865999 abstract "A luminescent conjugated microporous polymer (BCMP-3) has been synthesized in high yield by a carbon-carbon coupling reaction using triarylboron as a building unit. BCMP-3 was fully characterized by using powder X-ray diffraction analysis, Fourier transform infrared spectroscopy, (13) C solid-state NMR spectroscopy, field emission scanning electron microscopy, thermogravimetric analysis, and nitrogen and carbon dioxide adsorption. The new three-dimensional conjugated framework possess a high Brunauer-Emmett-Teller (BET) specific surface area up to 950 m(2) g(-1) with a pore volume of 0.768 cm(3) g(-1) , good stability, and abundant boron sites in the skeleton. Under excited-light irradiation, BCMP-3 exhibits strong fluorescent emission at 488 nm with a high absolute quantum yield of 18 % in the solid state. Polymer BCMP-3 acts as a colorimetric and fluorescent chemosensor with high sensitivity and selectivity for F(-) over other common anions. In addition, the polymer also works as an adsorbent for F(-) removal and shows good adsorption capacities of up to 24 mg g(-1) at equilibrium F(-) concentrations of 16 mg L(-1) and a temperature of 298 K. The adsorption kinetics and isotherm were analyzed by fitting experimental data with pseudo-second-order kinetics and Langmuir equations. Furthermore, we highlight that BCMP-3 is an adsorbent for fluoride removal that can be efficiently reused many times without loss of adsorption efficiency." @default.
- W2114865999 created "2016-06-24" @default.
- W2114865999 creator A5000359400 @default.
- W2114865999 creator A5010430384 @default.
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- W2114865999 creator A5049588474 @default.
- W2114865999 creator A5056674934 @default.
- W2114865999 creator A5075969100 @default.
- W2114865999 date "2015-10-14" @default.
- W2114865999 modified "2023-10-15" @default.
- W2114865999 title "Triarylboron-Linked Conjugated Microporous Polymers: Sensing and Removal of Fluoride Ions" @default.
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