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• W2115038296 abstract "Rare-earth inorganic orthophosphates have been attracting considerable research interest because of their significant luminescent properties. In the present work, we employed a facile oil-bath route to successfully realize phase-controlled synthesis of CePO4 nanocrystals. The reactions were carried out at 110 °C for 30 min. The phases of the as-obtained products were determined by X-ray powder diffraction (XRD) analyses. Experiments showed that a mixed phase of hexagonal and monoclinic CePO4 was prepared at the EG/H2O volume ratio of 14/5, keeping the introduced EG/H2O total volume of 19 mL unchanged. Hexagonal CePO4 nanocrystals were obtained at the EG/H2O volume ratio below 14/5; while at a volume ratio above 14/5, monoclinic ones were produced. Interestingly, the morphology of the final product underwent a change from long nanorods, to short nanorods, to nanorod bundles, to shuttle-like nanocrystals, and finally to spheroid nanocrystals with the increase of the EG/H2O volume ratio. Furthermore, the optical performances of the final products with different forms were also investigated." @default.
• W2115038296 created "2016-06-24" @default.
• W2115038296 creator A5002978395 @default.
• W2115038296 creator A5033334181 @default.
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• W2115038296 date "2014-08-05" @default.
• W2115038296 modified "2023-10-17" @default.
• W2115038296 title "Phase-controllable synthesis, shape evolution and optical performances of CePO₄nanocrystals via a simple oil-bath route" @default.
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• W2115038296 doi "https://doi.org/10.1039/c4ra07052f" @default.
• W2115038296 hasPublicationYear "2014" @default.
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