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- W2115046075 abstract "Abstract A principally new exploit of ionic liquids as an alternative reaction medium in the synthesis of cyano‐bridged coordination‐polymer nanoparticles is reported. Stable colloid solutions containing nanoparticles of cyano‐bridged molecule‐based magnets, M 3 [Fe(CN) 6 ] 2 /[RMIM][BF 4 ] (M 2+ =Ni, Cu, Co) and Fe 4 [Fe(CN) 6 ] 3 /[RMIM][BF 4 ] (R=1‐butyl (BMIM), 1‐decyl (DMIM)), were prepared in the corresponding 1‐R‐3‐methylimidazolium tetrafluoroborate [RMIM][BF 4 ], which acts as both a stabilising agent and a solvent. By varying the length of the N‐alkyl chain on the imidazolium cation of [RMIM] + and the temperature, the growing process can be controlled to produce nanoparticles of different sizes. By studying the magnetic properties of frozen colloids it is shown that the relaxation of magnetisation is strongly influenced by interparticle interactions, which leads to the appearance of spin‐glass‐like dynamics in these systems." @default.
- W2115046075 created "2016-06-24" @default.
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- W2115046075 date "2006-04-20" @default.
- W2115046075 modified "2023-10-17" @default.
- W2115046075 title "Synthesis of Cyano-Bridged Magnetic Nanoparticles Using Room-Temperature Ionic Liquids" @default.
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- W2115046075 doi "https://doi.org/10.1002/chem.200500805" @default.
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