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- W2115049735 abstract "Abstract The use of (R)-methyl para-tolylsulfoxide as a chiral auxiliary in a novel synthesis of a key intermediate en route to mevinic acid-type hypocholestemic agents is described. The synthesis is short and simple consisting of eight steps to yield enantiomerically pure β-silyloxy-δ-lactone. The chiral sulfoxide used in the synthesis was obtained via a straightforward biooxidation of methyl para-tolylsulfide using bakers' yeast (Saccharomyces cerevisiae NCYC 73). The biotransformation involves the use of whole cells and affords the sulfoxide in good yield and with high stereoselectivity." @default.
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- W2115049735 date "1995-11-01" @default.
- W2115049735 modified "2023-09-27" @default.
- W2115049735 title "Bakers' yeast oxidation of methyl para-tolylsuifide: Synthesis of a chiral intermediate in the preparation of the mevinic acid-type hypocholestemic agents" @default.
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- W2115049735 doi "https://doi.org/10.1016/0040-4020(95)00819-t" @default.
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