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- W2115110474 abstract "Abstract A series of easily accessible diphosphane compounds 1 − 4 , based on bisphenol A derived backbones, has been prepared. A straightforward two‐step synthetic route has been employed to obtain these new ligands in good yields from cheap starting materials. Molecular structures for both compound 2 and its oxidized form ( 5· H 2 O) have been determined and are discussed in detail. The coordination of ligand 2 to palladium, platinum, and rhodium precursors has been studied by NMR spectroscopy as well as X‐ray crystallography. The molecular structures of the face‐to‐face dimeric species [{PdCl(CH 3 )(2)} 2 ] ( 6 ), [{PtCl 2 ( 2 )} 2 ] ( 7 ), and [{RhCl(CO)( 2 )} 2 ] ( 8 ) are described in detail. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)" @default.
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- W2115110474 date "2003-12-01" @default.
- W2115110474 modified "2023-10-14" @default.
- W2115110474 title "New Diphosphane Ligands Based on Bisphenol A Backbones − Synthesis and Coordination Chemistry" @default.
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- W2115110474 doi "https://doi.org/10.1002/ejic.200300419" @default.
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