Matches in SemOpenAlex for { <https://semopenalex.org/work/W2115188869> ?p ?o ?g. }
- W2115188869 endingPage "1854" @default.
- W2115188869 startingPage "1845" @default.
- W2115188869 abstract "Treatment of [NiII(tn)3][OTs]2 or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K4MIV(CN)8 · 2H2O (MIV = Mo, W) affords one-dimensional chains of {[trans-NiII(tn)2(OH2)][trans-NiII(tn)2][(μ-NC)3MIV(CN)5] · 6H2O} stoichiometry (MIV = Mo, 2; W, 3). An additional three-dimensional network, Cs4[CuII(OH2)4]2[CuII(NH3)]4[MoIV(CN)8]4 · 2H2O (4), is obtained by treating aqueous solutions of Cs3MoV(CN)8 with CuCl2 · 2H2O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the NiII and CuII centers present." @default.
- W2115188869 created "2016-06-24" @default.
- W2115188869 creator A5026256638 @default.
- W2115188869 creator A5060307181 @default.
- W2115188869 creator A5070814731 @default.
- W2115188869 creator A5074934551 @default.
- W2115188869 date "2005-10-01" @default.
- W2115188869 modified "2023-09-24" @default.
- W2115188869 title "One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: {[trans-NiII(tn)2(OH2)][trans-NiII(μ-NC)2(tn)2][(μ-NC)3MIV(CN)5]·6H2O} (MIV=Mo, W) and Cs4[CuII(OH2)4]2[CuII(NH3)]4[MoIV(CN)8]4·2H2O" @default.
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