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- W2115213612 abstract "Methane adsorption on Ga ion-exchanged ZSM-5 (Ga-ZSM-5) and In ion-exchanged ZSM-5 (In-ZSM-5) was investigated by temperature-programmed desorption in ultra high vacuum (UHV-TPD) to clarify the difference in the influence of water vapor on the selective catalytic reduction of NOx by methane. Methane was adsorbed on Ga-ZSM-5 and In-ZSM-5, and the adsorption heats of methane were estimated to be − 98 kJ/mol and − 132 kJ/mol for Ga-ZSM-5 and In-ZSM-5, respectively. The amount of methane adsorbed on Ga-ZSM-5 decreased considerably after the preadsorption of water, while little decrease was observed on In-ZSM-5. These results suggest that one of the reasons that the suppression of HC-SCR activity by water vapor is less severe on In-ZSM-5 than on Ga-ZSM-5, may be that competitive water adsorption is much more inhibiting to methane adsorption on Ga-ZSM-5 than it is on In-ZSM-5." @default.
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- W2115213612 date "1995-08-01" @default.
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- W2115213612 title "Relationship between methane adsorption and selective catalytic reduction of nitrogen oxide by methane on gallium and indium ion-exchanged ZSM-5" @default.
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- W2115213612 doi "https://doi.org/10.1016/0926-3373(95)00016-x" @default.
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