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• W2115222002 abstract "Abstract Two novel supramolecular building blocks, namely cis ‐ and trans ‐symmetric zinc–porphyrins bearing Hamilton receptors as their focal points ( 10 and 15 ), were self‐assembled with (i) first‐, second‐ and third‐generation depsipeptide cyanurates ( 21 – 23 ); (ii) second‐generation dendrofullerene ( 24 ), and (iii) cyanuric acid substituted fullerene ( 20 ), and probed in a series of photophysical investigations. Importantly, an overall 1:2 stoichiometry was confirmed with binding constants K n , and Hill coefficients n H that indicate remarkable cooperativities. As a general feature, stronger binding evolves from the trans ‐symmetric porphyrin isomer, although the increased steric demand of the depsipeptide ligandsmeans that the binding constants decrease with each generation. The self‐assembly of 10 or 15 with 20 affords novel electron donor–acceptor hybrids that reveal, upon excitation,intra‐hybrid charge‐transfer events." @default.
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• W2115222002 date "2010-07-26" @default.
• W2115222002 modified "2023-09-23" @default.
• W2115222002 title "Self-Assembling Depsipeptide Dendrimers and Dendritic Fullerenes with New cis- and trans-Symmetric Hamilton Receptor Functionalized Zn-Porphyrins: Synthesis, Photophysical Properties and Cooperativity Phenomena" @default.
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• W2115222002 doi "https://doi.org/10.1002/ejoc.201000233" @default.
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