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• W2115282559 abstract "Abstract The oxidative cyclization of 3,4-dimethoxyphenyl 3,4-dimethoxyphenylacetate, through intramolecular biphenyl bond formation, was successful and gave the target seven-membered lactone in good yield (85–86%). All other ester substrates gave biphenyl products or their further oxidized products via intermolecular coupling of their radical cation intermediate with the neutral substrate. It appears that matching of the oxidation potentials and nucleophilicity of the two phenyl rings, the positioning of the ring substituents and the ease of E to Z isomerization about the ester C–O bond are important factors contributing to these product outcomes." @default.
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• W2115282559 date "2007-11-01" @default.
• W2115282559 modified "2023-10-16" @default.
• W2115282559 title "Intramolecular versus intermolecular oxidative couplings of ester tethered di-aryl ethers" @default.
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• W2115282559 doi "https://doi.org/10.1016/j.tet.2007.08.082" @default.
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