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- W2115412361 abstract "Abstract The ligand 1 , based on the [1,1,1,1]cyclophane skeleton and bearing two pyridine units as monodentate coordination sites on the same face of the backbone, leads, in the presence of ZnX 2 (X = Cl, Br or I) complexes, to three isostructural neutral metallamacrocycles with an M/L ratio of 2:2. All three binuclear complexes have been characterised in the solid state by single‐crystal X‐ray diffraction. All three metallamacrocycles possess a roof‐shaped geometry affording a pocket with a single opening. The latter is occupied by solvent molecules in the solid state. A correlation between the size of the halide and dimensions of the pocket is described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)" @default.
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- W2115412361 date "2003-03-20" @default.
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- W2115412361 title "Design and Structural Analysis of Metallamacrocycles Based on Zinc Halides and a V‐Shaped Bismonodentate Ligand of the Cyclophane Type" @default.
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- W2115412361 doi "https://doi.org/10.1002/ejic.200390167" @default.
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