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- W2115550112 endingPage "9869" @default.
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- W2115550112 abstract "Abstract The three‐component [3+2+1] cycloaddition of epoxides, imines, and carbon monoxide to produce 1,3‐oxazinan‐4‐ones has been developed by using [HCo(CO) 4 ] as the catalyst. The reaction occurs for a wide variety of imines and epoxides, under 60 bar of CO pressure at 50 °C, to produce 1,3‐oxazinan‐4‐ones with different substitution patterns in high yields, and provides an efficient and atom‐economic route to heterocycles from simple and readily available starting materials. A plausible mechanism involves [HCo(CO) 4 ]‐induced ring‐opening of the epoxide, followed by sequential addition of carbon monoxide and the imine, and then ring closure to form the product accompanied by regeneration of [HCo(CO) 4 ]." @default.
- W2115550112 created "2016-06-24" @default.
- W2115550112 creator A5048355915 @default.
- W2115550112 creator A5051140330 @default.
- W2115550112 date "2014-07-18" @default.
- W2115550112 modified "2023-10-18" @default.
- W2115550112 title "[HCo(CO)<sub>4</sub>]-Catalyzed Three-component Cycloaddition of Epoxides, Imines, and Carbon Monoxide: Facile Construction of 1,3-Oxazinan-4-ones" @default.
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- W2115550112 doi "https://doi.org/10.1002/anie.201403998" @default.
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