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• W2115638431 endingPage "461" @default.
• W2115638431 startingPage "423" @default.
• W2115638431 abstract "This review discusses the reactivities and thermodynamics of small-size-specific transition metal clusters and focuses on thermodynamic information, which has not been comprehensively discussed before. Because of this focus, guided-ion-beam mass spectrometry was used to acquire much of the data. The details of this technique and the associated data analysis methods are provided. Results on the stabilities of bare transition metal clusters are provided for neutral, cationic, and anionic species. Implications for the electronic and geometrical structures are discussed, as well as the extrapolation of these values to bulk phase behavior. Detailed results for reactions of transition metal clusters with D2 and the oxygen donors O2 and CO2 are reviewed. Available bond energies between size-specific clusters and one D atom and one and two O atoms are compiled, and their implications are evaluated and favorably compared with bulk phase analogs. Several additional thermodynamic studies of various cluster systems are also discussed." @default.
• W2115638431 created "2016-06-24" @default.
• W2115638431 creator A5073336335 @default.
• W2115638431 date "2001-10-01" @default.
• W2115638431 modified "2023-10-05" @default.
• W2115638431 title "R<scp>EACTIONS AND</scp>T<scp>HERMOCHEMISTRY OF</scp>S<scp>MALL</scp>T<scp>RANSITION</scp>M<scp>ETAL</scp>C<scp>LUSTER</scp>I<scp>ONS</scp>" @default.
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