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- W2115655227 abstract "We report a rhodium(II)-catalyzed highly enantioselective 1,3-dipolar cycloaddition reaction between the carbonyl moiety of tropone and carbonyl ylides to afford troponoids in good to high yields with excellent enantioselectivity. We demonstrate that α-diazoketone-derived carbonyl ylides, in contrast to carbonyl ylides derived from diazodiketoesters, undergo [6+3] cycloaddition reactions with tropone to yield the corresponding bridged heterocycles with excellent stereoselectivity." @default.
- W2115655227 created "2016-06-24" @default.
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- W2115655227 date "2015-05-08" @default.
- W2115655227 modified "2023-10-17" @default.
- W2115655227 title "Rhodium(II)-Catalyzed Enantioselective Synthesis of Troponoids" @default.
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- W2115655227 doi "https://doi.org/10.1002/anie.201502233" @default.
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