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- W2115802891 abstract "Abstract When subjected to proton catalysis, the α‐alkynylestradiol methyl ethers 1a and 1b furnish the Rupe or Meyer‐Schuster rearrangement products 2 , 4 , and 5a . In the presence of sulfuric acid, α‐ethynylestradiol 3‐methyl ether ( 1a ) is converted into the D‐homosteroid 3a . The use of deuterated acids gives rise to the formation of the corresponding deuterated steroids 2b , 2c , 3b , and 5b . Some mechanistic implications of these results are also discussed." @default.
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- W2115802891 date "1993-10-12" @default.
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- W2115802891 title "Proton Acid-induced Rearrangements of α-Alkynylestradiol Methyl Ethers" @default.
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- W2115802891 doi "https://doi.org/10.1002/jlac.1993199301176" @default.
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