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- W2115854208 abstract "A versatile, efficient route to ribosylhopane with control over all asymmetric carbon atoms of the side-chain is presented. The synthesis is based on two chain elongations starting from diploptene by subsequent additions of two acetylenic moieties. In a key step a keto-propiolate is stereoselectively reduced to the corresponding hydroxy-propiolate by means of a chiral oxazaborolidine assisted hydroboration. This synthetic protocol represents a useful tool for the access to natural and unnatural bacteriohopanepolyol derivatives of biological interest as well as to labeled ribosylhopane and bacteriohopanetetrol for biosynthetic studies.Download : Download full-size image" @default.
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- W2115854208 date "1999-08-01" @default.
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- W2115854208 title "Synthesis of ribosylhopane, the putative biosynthetic precursor of bacterial triterpenoids of the hopane series" @default.
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