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- W2115890490 abstract "Binuclear iron(II)–vanadium(IV) complexes of types [FeL3VO(acac)]1 and [FeL3VO(diam)]PF62 have been prepared where HL is PhNNC(R)NOH with R = Ph(HL1) or Me(HL2), Hacac is acetylacetone and diam is 2,2′-bipyridine (bipy), 1,10-phenanthroline or 3,5-dimethyl-1-(2-pyridyl)pyrazole. Complexes of type 1 are obtained from Na[FeL3]·H2O and [VO(acac)2] and 2 by adding diam to acidified 1. The crystal structure of [FeL13VO(bipy)] PF6 has been determined. The low-spin iron(II) atom is facially tris chelated in the Fe(N,N)3 fashion and the three pendant oximato oxygen atoms engage the vanadium atom which is also bonded to an oxo oxygen and bipy nitrogen atoms. The VO4N2 co-ordination sphere is distorted octahedral. The trans influence of the oxo oxygen lengthens a V–O(oximate) bond by 0.2 Å. The complexes behave as one-electron paramagnets due to the VO2+ centre. Their ESR spectra are axial with g∥ < g⊥. The 51V hyperfine interaction follows the trend 1 > 2." @default.
- W2115890490 created "2016-06-24" @default.
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- W2115890490 date "1991-01-01" @default.
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- W2115890490 title "New binuclear iron–vanadium complexes of arylazo oximates. Crystal structure of [Fe(PhNNCPhNO)<sub>3</sub>VO(bipy)]PF<sub>6</sub>(bipy = 2,2′-bipyridine)" @default.
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- W2115890490 doi "https://doi.org/10.1039/dt9910003217" @default.
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