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- W2116043602 abstract "The kinetics of the anodic oxidation of propylene in acetonitrile have been investigated. At low potentials the rate controlling step is electron transfer while at high potentials the two-electron process becomes diffusion controlled. The initial products of the electrode process are the allyl carbonium ion and the proton. The carbonium ion is an extremely short-lived species and disappears by a series of fast reactions; N-allylacetamide is the major product under all conditions investigated. The proton also gives rise to a series of products but its reactions are much slower and it may be identified using electrochemical techniques or titrated with base." @default.
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- W2116043602 date "1972-04-01" @default.
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- W2116043602 title "The partial anodic oxidation of propylene in acetonitrile" @default.
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- W2116043602 doi "https://doi.org/10.1016/s0022-0728(72)80453-4" @default.
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