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- W2116074206 abstract "Isoxazol-5(2H)-ones undergo Michael addition to propiolate esters under mildly basic conditions to form N-alkenylisoxazolones, with small amounts of the isomeric C- or O-alkylated materials. The former lose carbon dioxide when subjected to flash vacuum pyrolysis or photolysis, and give pyrroles in ca 40% yields. Minor accompanying products arise from capture of the intermediate carbene by solvent, or from hydrogen atom abstraction." @default.
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- W2116074206 date "2001-08-16" @default.
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- W2116074206 title "The synthesis of pyrroles from N-alkenylisoxazol-5(2H)-ones" @default.
- W2116074206 doi "https://doi.org/10.3998/ark.5550190.0002.708" @default.
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