Matches in SemOpenAlex for { <https://semopenalex.org/work/W2116301986> ?p ?o ?g. }
- W2116301986 endingPage "585" @default.
- W2116301986 startingPage "582" @default.
- W2116301986 abstract "Abstract Side‐chain‐oxidized C‐28‐sterol 1 and one new pregnane metabolite 2 were isolated from eastern Pacific Muricea spp. The C‐24(28)‐epoxide functionality is a key intermediate in the C‐24‐dealkylation mechanism of the conversion of phytosterol to cholesterol by phytophagous insects. Certain marine invertebrates share this dealkylation pathway; however, such a key epoxide feature has not yet been found in a naturally occurring sterol from marine invertebrates. The unusual oxidation pattern of the side chain of 1 encourages speculation about its biogenesis and converts this non‐zooxanthellate gorgonia into an interesting candidate organism for biosynthetic studies on C‐24‐dealkylation of phytosterols in octocorals. The (22 S )‐22‐hydroxy group, after 24‐dealkylation of 1 , may be an advantageous functionalization in the side‐chain cleavage to C‐21‐pregnane steroids in Muricea spp. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
- W2116301986 created "2016-06-24" @default.
- W2116301986 creator A5009865059 @default.
- W2116301986 creator A5020713619 @default.
- W2116301986 creator A5034477873 @default.
- W2116301986 creator A5061131166 @default.
- W2116301986 creator A5063553934 @default.
- W2116301986 creator A5071693638 @default.
- W2116301986 date "2006-01-18" @default.
- W2116301986 modified "2023-10-18" @default.
- W2116301986 title "Muriceanol, a 24(28)-Epoxide Sterol Link in the Carbon Flux Toward Side-Chain Dealkylation of Sterols" @default.
- W2116301986 cites W1558813157 @default.
- W2116301986 cites W1964644658 @default.
- W2116301986 cites W1977396869 @default.
- W2116301986 cites W1997469941 @default.
- W2116301986 cites W2013703359 @default.
- W2116301986 cites W2018017202 @default.
- W2116301986 cites W2020197153 @default.
- W2116301986 cites W2026638613 @default.
- W2116301986 cites W2046447946 @default.
- W2116301986 cites W2049439349 @default.
- W2116301986 cites W2106216001 @default.
- W2116301986 cites W2497179672 @default.
- W2116301986 cites W2950631759 @default.
- W2116301986 cites W2951855235 @default.
- W2116301986 cites W4254119273 @default.
- W2116301986 doi "https://doi.org/10.1002/ejoc.200500775" @default.
- W2116301986 hasPublicationYear "2006" @default.
- W2116301986 type Work @default.
- W2116301986 sameAs 2116301986 @default.
- W2116301986 citedByCount "17" @default.
- W2116301986 countsByYear W21163019862012 @default.
- W2116301986 countsByYear W21163019862014 @default.
- W2116301986 countsByYear W21163019862015 @default.
- W2116301986 countsByYear W21163019862016 @default.
- W2116301986 countsByYear W21163019862019 @default.
- W2116301986 countsByYear W21163019862020 @default.
- W2116301986 countsByYear W21163019862021 @default.
- W2116301986 crossrefType "journal-article" @default.
- W2116301986 hasAuthorship W2116301986A5009865059 @default.
- W2116301986 hasAuthorship W2116301986A5020713619 @default.
- W2116301986 hasAuthorship W2116301986A5034477873 @default.
- W2116301986 hasAuthorship W2116301986A5061131166 @default.
- W2116301986 hasAuthorship W2116301986A5063553934 @default.
- W2116301986 hasAuthorship W2116301986A5071693638 @default.
- W2116301986 hasConcept C104317684 @default.
- W2116301986 hasConcept C131934819 @default.
- W2116301986 hasConcept C161790260 @default.
- W2116301986 hasConcept C164361826 @default.
- W2116301986 hasConcept C172269249 @default.
- W2116301986 hasConcept C178790620 @default.
- W2116301986 hasConcept C185592680 @default.
- W2116301986 hasConcept C18903297 @default.
- W2116301986 hasConcept C204921945 @default.
- W2116301986 hasConcept C2776920199 @default.
- W2116301986 hasConcept C2777477808 @default.
- W2116301986 hasConcept C2778163477 @default.
- W2116301986 hasConcept C2778718757 @default.
- W2116301986 hasConcept C2779718769 @default.
- W2116301986 hasConcept C521977710 @default.
- W2116301986 hasConcept C55493867 @default.
- W2116301986 hasConcept C71240020 @default.
- W2116301986 hasConcept C86803240 @default.
- W2116301986 hasConceptScore W2116301986C104317684 @default.
- W2116301986 hasConceptScore W2116301986C131934819 @default.
- W2116301986 hasConceptScore W2116301986C161790260 @default.
- W2116301986 hasConceptScore W2116301986C164361826 @default.
- W2116301986 hasConceptScore W2116301986C172269249 @default.
- W2116301986 hasConceptScore W2116301986C178790620 @default.
- W2116301986 hasConceptScore W2116301986C185592680 @default.
- W2116301986 hasConceptScore W2116301986C18903297 @default.
- W2116301986 hasConceptScore W2116301986C204921945 @default.
- W2116301986 hasConceptScore W2116301986C2776920199 @default.
- W2116301986 hasConceptScore W2116301986C2777477808 @default.
- W2116301986 hasConceptScore W2116301986C2778163477 @default.
- W2116301986 hasConceptScore W2116301986C2778718757 @default.
- W2116301986 hasConceptScore W2116301986C2779718769 @default.
- W2116301986 hasConceptScore W2116301986C521977710 @default.
- W2116301986 hasConceptScore W2116301986C55493867 @default.
- W2116301986 hasConceptScore W2116301986C71240020 @default.
- W2116301986 hasConceptScore W2116301986C86803240 @default.
- W2116301986 hasIssue "3" @default.
- W2116301986 hasLocation W21163019861 @default.
- W2116301986 hasOpenAccess W2116301986 @default.
- W2116301986 hasPrimaryLocation W21163019861 @default.
- W2116301986 hasRelatedWork W1993965573 @default.
- W2116301986 hasRelatedWork W2014983802 @default.
- W2116301986 hasRelatedWork W2018662109 @default.
- W2116301986 hasRelatedWork W2019914283 @default.
- W2116301986 hasRelatedWork W2087016384 @default.
- W2116301986 hasRelatedWork W2116301986 @default.
- W2116301986 hasRelatedWork W2164893689 @default.
- W2116301986 hasRelatedWork W2257733353 @default.
- W2116301986 hasRelatedWork W2949568529 @default.
- W2116301986 hasRelatedWork W2951044641 @default.
- W2116301986 hasVolume "2006" @default.
- W2116301986 isParatext "false" @default.
- W2116301986 isRetracted "false" @default.