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- W2116331367 abstract "A product study on the reactivity of a 1,1-diarylalkoxyl radical bearing 2,2-diphenylcyclopropyl groups in the para-positions has been carried out. The exclusive formation of a product deriving from cyclopropyl ring-opening has been observed, indicating that 1,1-diarylalkoxyl radicals exist in equilibrium with a bridged 1-oxaspiro[2,5]octadienyl radical. This represents the first experimental evidence in support of the stepwise nature of the O-neophyl rearrangement of 1,1-diarylalkoxyl radicals." @default.
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- W2116331367 date "2010-08-01" @default.
- W2116331367 modified "2023-09-26" @default.
- W2116331367 title "The O-neophyl rearrangement of 1,1-diarylalkoxyl radicals. Experimental evidence for the formation of an intermediate 1-oxaspiro[2,5]octadienyl radical" @default.
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- W2116331367 doi "https://doi.org/10.1016/j.tetlet.2010.05.149" @default.
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