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• W2116424897 abstract "Syntheses of three regioisomers of aromatic-substituted phosphinyl-oxazolinyl-[2.2]paracyclophanes, pseudo-geminal, pseudo-ortho, and ortho, have been carried out or, in the latter two cases, newly developed. It has, therefore, been demonstrated that all aromatic-substituted isomers relevant for use as chelating ligands for asymmetric catalysis are accessible. These P,N-ligands, along with their diastereoisomers, were shown to exhibit widely differing activity and enantioselectivity (up to 89% ee) in the Pd-catalyzed asymmetric allylic alkylation reaction." @default.
• W2116424897 created "2016-06-24" @default.
• W2116424897 creator A5007308411 @default.
• W2116424897 creator A5014244270 @default.
• W2116424897 date "2006-05-18" @default.
• W2116424897 modified "2023-10-14" @default.
• W2116424897 title "Synthesis of Pseudo-<i>geminal</i>-, Pseudo-<i>ortho</i>-, and <i>ortho-</i>Phosphinyl-oxazolinyl-[2.2]paracyclophanes for Use as Ligands in Asymmetric Catalysis" @default.
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• W2116424897 doi "https://doi.org/10.1021/jo060668h" @default.
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