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- W2116465765 abstract "Eremanthine (1), an abundant natural substance, was transformed in four steps into diol 5. Hydrogenolysis of 5 (55 psi of H2, Pd/C, 30 min) furnished 7. Hydrogenation of 5 using a low hydrogen pressure (5 psi) and a short reaction time (15 min) led to a mixture of 6 and 7 (3:1). Compounds 6 and 7 were then transformed respectively to the alpha-methylene-gamma-lactones micheliolide (9) and 1(R),10(R)-dihydromicheliolide (8), after elimination of methanol." @default.
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- W2116465765 date "2005-08-01" @default.
- W2116465765 modified "2023-10-16" @default.
- W2116465765 title "Chemical transformations of eremanthine: synthesis of micheliolide and 1(R),10(R)-dihydromicheliolide" @default.
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- W2116465765 doi "https://doi.org/10.1590/s0103-50532005000500012" @default.
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