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- W2116478148 abstract "Cu-containing conversion electrodes have received much study as high capacity electrodes for lithium-ion batteries, but many suffer from poor reversibility. The electrochemical properties of the copper hydroxysulfate compound, Cu4(OH)6SO4, more commonly known as the mineral brochantite and as a patina constituent on the Statue of Liberty, were investigated. Nanostructured brochantite was synthesized using precipitation and microwave-assisted hydrothermal reactions and evaluated in half-cells with Li metal counter electrodes. Reversible capacities >400 mAh/g corresponding to the 2 electron reduction of Cu2+ and discharge potential of 1.8 V versus Li/Li+ were observed in brochantite with a nanoplate morphology. Detailed characterization using X-ray diffraction, scanning and transmission electron microscopy, and X-ray photoelectron spectroscopy was performed to better understand the conversion process." @default.
- W2116478148 created "2016-06-24" @default.
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- W2116478148 date "2013-11-18" @default.
- W2116478148 modified "2023-10-17" @default.
- W2116478148 title "Electrochemical Properties of Nanostructured Copper Hydroxysulfate Mineral Brochantite upon Reaction with Lithium" @default.
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- W2116478148 doi "https://doi.org/10.1021/nl403286m" @default.
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