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- W2116489273 abstract "Abstract 2-Methoxypropenal in acid media undergoes general acid-catalyzed hydrolysis with formation of 2-oxopropanal. The kinetics of this reaction were studied, the rate constants established, and a reaction mechanism is suggested. Hydrolysis of 2-methoxypropenal is governed by a mechanism of the vinyl ether type, and the presence of the aldehyde group causes a decrease in the reaction rate. The analogy of the acid-catalyzed hydrolysis of 2-methoxypropenal to that of a vinyl ether was shown by the solvent isotope-effect, kD/kH = 0.41, and the value of the Bronsted exponent, α = 0.60. The activation parameters found and quantum-chemical calculations of charge distribution in 2-methoxypropenal and other model compounds were also utilized to explain the mechanism of the acid-catalyzed hydrolysis of the title compound." @default.
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- W2116489273 date "1983-04-01" @default.
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- W2116489273 title "Acid-catalyzed hydrolysis of 2-methoxypropenal" @default.
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- W2116489273 doi "https://doi.org/10.1016/0008-6215(83)88137-3" @default.
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