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• W2116551031 abstract "One electron at a time: Half-sandwich organometallic cyclopentadienyl–IrIII complexes containing N,N-chelated ligands can catalyze the reduction of quinones (Q), such as vitamin K3, to semiquinones (Q.−) by coenzyme NADH (see picture). DFT calculations suggest that the mechanism involves hydride transfer followed by two one-electron transfers and the unusual IrII oxidation state as a key transient intermediate." @default.
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• W2116551031 date "2013-03-07" @default.
• W2116551031 modified "2023-10-06" @default.
• W2116551031 title "Reduction of Quinones by NADH Catalyzed by Organoiridium Complexes" @default.
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• W2116551031 doi "https://doi.org/10.1002/anie.201300747" @default.
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