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• W2116580504 abstract "A novel method for the preparation of alkyl azides from alcohols by way of oxidation–reduction condensation is described. In this reaction, the sterically-hindered tert-alkyl phosphinites that are prepared from the corresponding alcohols are converted into tert-alkyl azides with almost complete inversion of their stereochemistry: the obtained alkyl azides are then successfully reduced to afford the corresponding amines on treatment with LiAlH4, thus, a versatile method for the preparation of chiral amines from the corresponding chiral alcohols is established." @default.
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• W2116580504 date "2007-07-01" @default.
• W2116580504 modified "2023-09-30" @default.
• W2116580504 title "Conversion of tertiary alcohols to tert-alkyl azides by way of quinone-mediated oxidation–reduction condensation using alkyl diphenylphosphinites" @default.
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• W2116580504 doi "https://doi.org/10.1016/j.tet.2007.03.176" @default.
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