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• W2116683917 endingPage "1263" @default.
• W2116683917 startingPage "1263" @default.
• W2116683917 abstract "Hierarchical rope-like structures based on Co–Fe layered double hydroxide (LDH) nanosheets were synthesized by the coprecipitation method from a hexagonal lyotropic liquid crystal (LLC) nanoreactor, and were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric (TG) and inductively coupled plasma (ICP) analyses. It was found that the rope-like LDH structures were composed of LDH nanosheets with a lateral size of about 200–400 nm and an average thickness of 4.47 nm in the form of face-to-edge interactions. The length and the diameter of the rope-like assemblies were about 3–6 μm and 150–300 nm, respectively, and their aspect ratio was as high as 20. Interestingly, the LDH rope-like assemblies were ordered to form an array with the oriented directions parallel to each other. A formation mechanism for the hierarchical LDH structures in the LLC media was proposed. In addition, the catalytic activity of the hierarchical rope-like LDH assemblies for the oxidation reaction of the typical horseradish peroxidase (HRP) substrate, 3,3′,5,5′-tetramethylbenzidine (TMB), was examined, and results revealed that they had a higher oxidase-like catalytic activity towards the oxidization of TMB by dissolved oxygen. We expect that the hierarchical rope-like LDHs can offer the potential applications in aqueous redox catalysts, biosensors, medical diagnostics and so on." @default.
• W2116683917 created "2016-06-24" @default.
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• W2116683917 date "2013-01-01" @default.
• W2116683917 modified "2023-10-16" @default.
• W2116683917 title "A hierarchical Co–Fe LDH rope-like nanostructure: facile preparation from hexagonal lyotropic liquid crystals and intrinsic oxidase-like catalytic activity" @default.
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• W2116683917 doi "https://doi.org/10.1039/c2tb00389a" @default.
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